Probably not unless you want to set log_statement=all and then parse log_directory/log_filename.
Transactions per second
Does TPS make any sense beyond when DBMS is running a "strict monoculture" application like OLTP with zero report generation? Because a five hour SELECT that joins 42 tables in addition to 37 hairy subqueries is just as much a transaction as is a 5 microsecond SELECT of one customer's records using a hash index, and an equally fast INSERT of three records.